Vanguard Group Inc. is walking out of the world's largest climate-finance alliance, marking the coalition's biggest defection to date as Republicans step up their threats against firms deemed hostile toward the fossil-fuel industry.

Vanguard's decision followed a "considerable period of review," according to a company statement Wednesday. Last week, 13 Republican state attorneys general asked federal energy officials to consider blocking Vanguard from buying utility stocks because of its relationships with anti-coal and anti-natural gas activists.

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